全文获取类型
收费全文 | 101篇 |
免费 | 15篇 |
国内免费 | 59篇 |
专业分类
大气科学 | 4篇 |
地球物理 | 8篇 |
地质学 | 119篇 |
海洋学 | 21篇 |
综合类 | 14篇 |
自然地理 | 9篇 |
出版年
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 2篇 |
2015年 | 4篇 |
2014年 | 5篇 |
2013年 | 6篇 |
2012年 | 7篇 |
2011年 | 7篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 5篇 |
2007年 | 4篇 |
2006年 | 11篇 |
2005年 | 7篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 10篇 |
2001年 | 5篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 8篇 |
1996年 | 4篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有175条查询结果,搜索用时 296 毫秒
11.
研究了大孔膦酸树脂对毒砂中主、次和痕量元素的吸附行为及洗脱条件,结合巯基棉和TBP柱分离技术,建立了两个分离流程。在J-A1160型多道直读光谱仪上实现了毒砂单矿物中包括主量元素Fe和As在内的20个元素测定。主量元素As和Fe的相对标准偏差(n为5~10)分别为1.03%和0.9%,其它元素在5%~11%范围。流程经实际试样分析验证,结果与化学法相符。 相似文献
12.
743阳离子交换快速分离——ICPS-PGS2单道扫描直读光谱仪测定地质样品中15个微量稀土元素 总被引:1,自引:0,他引:1
本文采用过氧化钠(Na_2O_2)熔样,743阳离子交换树脂快速分离,0.4mol/L柠檬酸25ml洗脱稀土,无需浓缩,即可用lCPS-PGS2单道扫描直读光谱仪直接测定15个微量稀土元素。在选择的最佳测量条件下,本法测定下限为0.005~g/ml(Eu)-0.50μg/ml(Ce),标准加入回收在88%—110%之间,样品分析精度为3.3%—17%,样品分析结果与参考值相符。本法适用于一般地质样品中微量稀土元素的例行分析。 相似文献
13.
化学注浆治理巨厚表土层立井井壁漏水 总被引:1,自引:0,他引:1
煤矿立井由于各种原因经常发生井壁渗漏水,严重影响正常的煤矿安全生产。邱集煤矿副立井表土层厚320m,为巨厚表土层,发生渗水后,采用改性脲醛树脂浆材成功进行了破壁注浆处理,将井筒的涌水量由10m3/h降至0.3m3/h左右。同时,注浆时浆液形成的帷幕能达到加固地层,减少地层压缩沉降量,排除生产安全隐患,保护井桶的作用。 相似文献
14.
GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物 总被引:2,自引:2,他引:2
采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2,4-二氯酚、2,4,6-三氯酚、五氯酚等6种酚类化合物,以乙腈作为洗脱剂,选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明,方法检出限为0.01-0.05mg/L,IL水的平均加标回收率为82.5%-95.0%,精密度(RSD,n=7)为3.6%-9.2%。方法用于实际地表水中痕量酚类化合物的检测,操作简单,有机溶剂用量少,分析效率高;萃取小柱可多次重复使用,分析成本低。 相似文献
15.
A new method for the quantification of different redox-species of molybdenum (V and VI) in seawater 总被引:1,自引:0,他引:1
A new method for the direct determination of reduced and oxidized Mo species (Mo (V) and Mo (VI)) in seawater was developed and used for the first time. The method includes the complexation of Mo (V) with tartrate, solid phase extraction of the Mo (V)–tartrate complex by a XAD 7HP resin, followed by elution with acidic acetone. In this study, the eluted Mo (V) was quantified by graphite furnace atomic absorption spectrometry. The detection limit of this protocol was on the order of 0.2 nM. The analytical precision was 10% of ~ 10 nM. This method was successfully applied to the determination of Mo (V) and Mo (VI) in surface and bottom waters at the head of Peconic River Estuary. Total Mo (Mo (V) + Mo (VI)) ranged from 100–120 nM in most bottom saline waters, and 2.5–15 nM for surface fresher waters. Concentrations of Mo (V) in these environments ranged from 0 nM to ~ 15 nM, accounting for 0%–15% of the total dissolved Mo pool. The time series experiments showed that the Mo speciation changed within 1 h after the water collection, and therefore it is strongly suggested that speciation analysis be carried out within the first 15 min. However, since these are the first Mo speciation data in concentration ranges typical of normal marine and coastal waters, additional research may be required to optimize the methodology and further explore Mo cycling mechanisms. 相似文献
16.
以P-350吸附于DA_(201)树脂上,制得了P-350浸渍树脂,通过柱层析法,试验了树脂吸附和解脱Ag,Cd的条件和干扰离子的影响。建立了P-350浸渍树脂分离-富集Ag,Cd体系,并应用于岩石样品分析中,效果较好。 相似文献
17.
18.
基于SPE与SPATT的水体中麻痹性贝类毒素检测方法构建与应用 总被引:1,自引:0,他引:1
为实现麻痹性贝类毒素(paralytic shellfish poisoning,PSP)的实时监控与提前预警,本研究构建了基于固相萃取技术(solid phase extraction,SPE)与固相吸附毒素跟踪技术(solid phase adsorption toxin tracking,SPATT)的水体中PSP检测方法,重点优化了吸附材料及前处理方法,评价了回收率、检出限等指标,并将方法应用于2019年春季秦皇岛山海关海域PSP消长过程的监测中,比较评估了两种方法的监控预警效果。结果表明:SPE方法选用ENVI-Carb 500mg/6mL固相萃取柱,过样体积为50mL,13种PSP组分的平均回收率为82.2%±10.0%、检出限为4.0-20.0ng/L;SPATT方法选用SP207大孔吸附树脂,洗脱时间为静置Id最佳,整体回收率约为9.2%;在实际应用中,结合产毒藻密度及贻贝富集毒素含量的变化,发现SPE方法的检测结果可实时表征海域PSP风险状况,对于贻贝中PSP的预警效果也显著优于SAPTT方法,后者不仅因监控方式相对滞后一个监测周期,且灵敏度及准确性均较差。对于秦皇岛海域,当SPE方法检测结果达到100ng STX eq/L时,该海域贻贝中PSP残留将具有潜在的食用安全风险,跟踪过程表明这一阈值可提前两周预警贻贝富集毒素含量超出我国限量标准(800μg STX eq/kg),这对于强化风险警示并制定防范措施具有积极作用。 相似文献
19.
以732凝胶型强酸性阳离子交换树脂,采用两种工艺方案进行了离子交换法制取无水氯酸锂小型实验研究。在小型实验的基础上,推荐了用离子交换法制得氯酸,然后再中和、脱水制取无水氯酸锂的工艺。在推荐的工艺下,进行了扩大试验,制得了主含量为99%,杂质及水分符合国外用户标准的无水氯酸锂产品。 相似文献
20.
Snow avalanches are a widespread natural phenomenon in steep mountain environments, where they modulate landscapes and frequently disturb forest stands. Such disturbances in trees have been used since the 1970s to retrospectively date avalanches, study their extent and reach, as well as to document their triggers. Although virtually every dendrogeomorphic paper is still based on the concepts established by Shroder (1978), important methodological improvements have been achieved in the field ever since and more particularly over the last decade. This study therefore reports on recent methodological progress and employs three different approaches (i.e. Shroder index value and Kogelnig-Mayer weighted index value) and different sets of signals in trees (i.e. inclusion of tangential rows of traumatic resin ducts as evidence of past avalanching) to record snow avalanche activity. Using 238 increment cores from 105 Picea abies (L.) Karst trees which colonize a snow avalanche path in the Romanian Carpathians, we illustrate possibilities and limitations of the different approaches for the period covered by the chronologies (1852–2013). In addition, we sampled 30 undisturbed P. abies trees from a forest stand north of the avalanche path, where no geomorphic disturbance was identified, so as to build a reference tree-ring chronology. The three avalanche chronologies constructed with the disturbed trees allow identification of past process activity, but results differ quite considerably in terms of avalanche frequency, number of reconstructed events and their temporal distribution. Depending on the approach used, 15 to 20 snow avalanches can be reconstructed, with the best results being obtained in the dataset including tangential rows of traumatic resin ducts. The addition of this anatomical feature, formed after mechanical impact enlarges the number of growth disturbances by 43.5%, and can thus explain the increase of reconstructed avalanches by one-third as compared to the results of the chronology using the “conventional” Shroder approach. 相似文献